Showing posts with label 水素爆発. Show all posts
Showing posts with label 水素爆発. Show all posts

Saturday, September 24, 2011

福島原発1号機格納容器につながる配管内の水素、濃度100%の可能性

9月23日のニュースではこの配管から1万ppm、つまり1%以上の濃度の水素ガスが検出された、とありました。福島作業員(と思われる方)のTweetでは4万ppm以上、つまり4%以上の濃度。水素濃度がが4%を超えると水素爆発する可能性が高くなるのですが、24日になって、もっととんでもない値らしい、ということをほかならぬ東電が認めました。

配管内のガスは100%水素であるかも知れない、というのです。

ちなみに、通常の大気中の水素濃度は2万分の1パーセントです。

時事通信9月24日付け記事:

福島第1原発1号機の格納容器につながる配管から1%を超える濃度の水素が検出された問題で、東京電力は24日、配管内部の気体はほとんどが水素である可能性が高いと発表した。東電の松本純一原子力・立地本部長代理は同日の記者会見で、「着火源がないので、直ちに爆発のリスクが高いとは言えない」と述べた。

 東電によると、23日午後に配管の出口部分の気体を複数回測定したところ、いずれも「水素を含む可燃性ガスが100%以上」との数字が出た。今後、水素だけを計れる測定器を用意し、正確な濃度を測定する方針。

この水素ガスはどのように発生したのか。1号機建屋が3月12日の午後に爆発したときには、原子炉内の燃料の被覆管材料のジルカロイ(ジルコニウム合金)が水蒸気と反応して水素を大量発生し、爆発につながった、とされています。が、既に燃料は溶融し制御棒も被覆管もいっしょくたに混ざって圧力容器の外に落ちていることを東電も認めています。被覆管のジルカロイのほかに水素の発生源はあるのでしょうか?

今回の1号機の配管の水素に関係あるかどうかは私には分かりませんが、沸騰した水に放射線を当てると放射線分解で水素が発生する可能性があることが、9月13日の毎日新聞に出ていました:

東京電力福島第1原発4号機で起きた原子炉建屋の爆発について、沸騰した使用済み核燃料プール内で、水の放射線分解が進んで、水素が大量発生したことが一因との分析を、東京大や日本原子力研究開発機構のチームがまとめた。放射線は、水を水素などに分解する。19日から北九州市で始まる日本原子力学会で発表する。

4号機のプールには、事故を起こした1~4号機の中で最も多い1535本の燃料棒が入っていた。東日本大震災発生当時、定期検査で運転停止していたが、津波で電源を喪失。冷却機能が失われ、地震発生から4日後の3月15日に爆発した。

水素 爆発を起こした1、3号機では原子炉内にあった燃料棒が損傷し水素が発生したとされるが、4号機の燃料棒に目立った損傷はなかった。東電は排気筒を共有する3号機から水素が流入して、4号機の水素爆発にいたったと推定している。

 しかし、チームは3号機と4号機の爆発に約20時間の差があることに注目し、他の要因があると推測。フラスコ内の水を室温、97度、沸騰状態の3段階にして、放射線を照射。発生した水素の濃度を調べたところ、97度で室温の1.5倍、沸騰状態で100倍となることが分かった。

 水素は空気中の濃度が4%を超えると爆発の危険性が出てくる。建物上部にたまった水蒸気は壁で冷やされて水に戻るが、水素は気体のままで空気中に占める割合が高まったとみられる。

 チームの勝村庸介・東大教授(放射線化学)は「3号機からの流入に加え、放射線分解が重なったのではないか。今後、実際の原子炉建屋やプールの規模で起こるのかを検証したい」と話す。

 東電は「理屈上はありうるが、爆発させるほど水素が大量発生するかどうかは不明」としている。

それで思い出したのが、1号機の原子炉建屋地下から一階に噴出していた(今もしているのかは不明)毎時4シーベルトの蒸気。地下水が沸騰していて、しかも溶融燃料が地下室のどこかに落ちているとしたら、そこから出た放射線が沸騰している汚染水を分解して水素を発生させている可能性はあるのでしょうか?

ただ、100%水素ということになると、水分解で出るもう片方、酸素が出ていない、ということでしょうから、まだ残っていた燃料の被覆管のジルカロイが反応している?(もう真夜中もいい加減過ぎましたので素人考え休むに似たり、休むことにします。)

それにしても、水素ガスが100%というのは何かの計測ミスであることを望みます。万一着火でもしたら、もう野田首相やそのほかの閣僚の方々が世界で言いまわっているらしい、「原発事故は収束の方向に向かっている」「冷温停止を前倒し」などという夢物語は、まあ夢で終わります。悪夢です。

Tuesday, April 5, 2011

ニューヨークタイムズ:米国が見る福島原発の新たな危機

(更新)

とりあえず記事のポイントいくつか:

  • この記事は、ニューヨークタイムスにリークされた、アメリカ原子力規制委員会の機密文書を基にしている。

  • 核燃料を冷やすために放水、注水し続けた海水が、かえって問題を大きくした可能性がある。

  • 使用済み核燃料貯蔵プールの使用済み核燃料自体が爆発で飛び散って、原子炉の周囲1.6キロにわたって飛散した可能性がある(4号機)。

  • 第1号機圧力容器内には水がまったくない可能性がある。核燃料の大部分が溶融して容器の下方にたまっている上、注ぎ込まれていた海水の塩分が邪魔をして、真水を注水して冷却しようとしても水が届いていない。

  • 格納容器自体に水を入れて(間接的に)圧力容器内の炉心を冷やそうとする現在の方式にも問題がある。格納容器は多量の水を恒常的に入れておくようには設計されていないため、今後強い余震などが発生した場合、格納容器が破損される可能性がある。

  • 炉心から出る放射線が水の分子を水素と酸素に分解する可能性がある。

---------------------------------------------

ニューヨークタイムズに出たばかりの記事です。例によって消えてしまう前に全文一応コピーしてお出しします。非常で注入した海水が圧力容器内の状態を更に悪くした可能性があること、それと、使用済み核燃料貯蔵プールから出た核燃料のかけらまたは粒子が、原子炉から1.6キロ先まで飛んだ可能性があること、などが目に付きました。私も読んでいる真っ最中です。抄訳できるだけ早くお出ししたいと思います。

ちなみに、東電は1号機の格納容器に窒素ガスを6000立方メートル、数日かけて注入する予定、と発表しました。1号機は圧力容器の温度が高いままでしたが、窒素ガスをあわてて注入すると言うことは格納容器内の水素発生が急激に増え、水素爆発の可能性が高まったためと思われます。

水素が多量発生する第一の場所は、燃料棒の被覆管のジルコニウムと高温の水蒸気が反応してできるもの: Zr + 2 H2O → ZrO2 + 2 H2

二つ目の場所は、溶融した炉心(”Corium")が圧力容器から格納容器に出てしまって、格納容器のコンクリートと反応する場合です。


U.S. Sees Array of New Threats at Japan’s Nuclear Plant (2011年4月5日)

United States government engineers sent to help with the crisis in Japan are warning that the troubled nuclear plant there is facing a wide array of fresh threats that could persist indefinitely, and that in some cases are expected to increase as a result of the very measures being taken to keep the plant stable, according to a confidential assessment prepared by the Nuclear Regulatory Commission.

Among the new threats that were cited in the assessment, dated March 26, are the mounting stresses placed on the containment structures as they fill with radioactive cooling water, making them more vulnerable to rupture in one of the aftershocks rattling the site after the earthquake and tsunami of March 11. The document also cites the possibility of explosions inside the containment structures due to the release of hydrogen and oxygen from seawater pumped into the reactors, and offers new details on how semimolten fuel rods and salt buildup are impeding the flow of fresh water meant to cool the nuclear cores.

In recent days, workers have grappled with several side effects of the emergency measures taken to keep nuclear fuel at the plant from overheating, including leaks of radioactive water at the site and radiation burns to workers who step into the water. The assessment, as well as interviews with officials familiar with it, points to a new panoply of complex challenges that water creates for the safety of workers and the recovery and long-term stability of the reactors.

While the assessment does not speculate on the likelihood of new explosions or damage from an aftershock, either could lead to a breach of the containment structures in one or more of the crippled reactors, the last barriers that prevent a much more serious release of radiation from the nuclear core. If the fuel continues to heat and melt because of ineffective cooling, some nuclear experts say, that could also leave a radioactive mass that could stay molten for an extended period.

The document, which was obtained by The New York Times, provides a more detailed technical assessment than Japanese officials have provided of the conundrum facing the Japanese as they struggle to prevent more fuel from melting at the Fukushima Daiichi plant. But it appears to rely largely on data shared with American experts by the Japanese.

Among other problems, the document raises new questions about whether pouring water on nuclear fuel in the absence of functioning cooling systems can be sustained indefinitely. Experts have said the Japanese need to continue to keep the fuel cool for many months until the plant can be stabilized, but there is growing awareness that the risks of pumping water on the fuel present a whole new category of challenges that the nuclear industry is only beginning to comprehend.

The document also suggests that fragments or particles of nuclear fuel from spent fuel pools above the reactors were blown “up to one mile from the units,” and that pieces of highly radioactive material fell between two units and had to be “bulldozed over,” presumably to protect workers at the site. The ejection of nuclear material, which may have occurred during one of the earlier hydrogen explosions, may indicate more extensive damage to the extremely radioactive pools than previously disclosed.

David A. Lochbaum, a nuclear engineer who worked on the kinds of General Electric reactors used in Japan and now directs the nuclear safety project at the Union of Concerned Scientists, said that the welter of problems revealed in the document at three separate reactors made a successful outcome even more uncertain.

“I thought they were, not out of the woods, but at least at the edge of the woods,” said Mr. Lochbaum, who was not involved in preparing the document. “This paints a very different picture, and suggests that things are a lot worse. They could still have more damage in a big way if some of these things don’t work out for them.”

The steps recommended by the nuclear commission include injecting nitrogen, an inert gas, into the containment structures in an attempt to purge them of hydrogen and oxygen, which could combine to produce explosions. The document also recommends that engineers continue adding boron to cooling water to help prevent the cores from restarting the nuclear reaction, a process known as criticality.

Even so, the engineers who prepared the document do not believe that a resumption of criticality is an immediate likelihood, Neil Wilmshurst, vice president of the nuclear sector at the Electric Power Research Institute, said when contacted about the document. “I have seen no data to suggest that there is criticality ongoing,” said Mr. Wilmshurst, who was involved in the assessment.

The document was prepared for the commission’s Reactor Safety Team, which is assisting the Japanese government and the Tokyo Electric Power Company, which owns the plant. It says it is based on the “most recent available data” from numerous Japanese and American organizations, including the electric power company, the Japan Atomic Industrial Forum, the United States Department of Energy, General Electric and the Electric Power Research Institute, an independent, nonprofit group.

The document contains detailed assessments of each of the plant’s six reactors along with recommendations for action. Nuclear experts familiar with the assessment said that it was regularly updated but that over all, the March 26 version closely reflected current thinking.

The assessment provides graphic new detail on the conditions of the damaged cores in reactors 1, 2 and 3. Because slumping fuel and salt from seawater that had been used as a coolant is probably blocking circulation pathways, the water flow in No. 1 “is severely restricted and likely blocked.” Inside the core itself, “there is likely no water level,” the assessment says, adding that as a result, “it is difficult to determine how much cooling is getting to the fuel.” Similar problems exist in No. 2 and No. 3, although the blockage is probably less severe, the assessment says.

Some of the salt may have been washed away in the past week with the switch from seawater to fresh water cooling, nuclear experts said.

A rise in the water level of the containment structures has often been depicted as a possible way to immerse and cool the fuel. The assessment, however, warns that “when flooding containment, consider the implications of water weight on seismic capability of containment.”

Experts in nuclear plant design say that this warning refers to the enormous stress put on the containment structures by the rising water. The more water in the structures, the more easily a large aftershock could rupture one of them.

Margaret Harding, a former reactor designer for General Electric, warned of aftershocks and said, “If I were in the Japanese’s shoes, I’d be very reluctant to have tons and tons of water sitting in a containment whose structural integrity hasn’t been checked since the earthquake.”

The N.R.C. document also expressed concern about the potential for a “hazardous atmosphere” in the concrete-and-steel containment structures because of the release of hydrogen and oxygen from the seawater in a highly radioactive environment.

Hydrogen explosions in the first few days of the disaster heavily damaged several reactor buildings and in one case may have damaged a containment structure. That hydrogen was produced by a mechanism involving the metal cladding of the nuclear fuel. The document urged that Japanese operators restore the ability to purge the structures of these gases and fill them with stable nitrogen gas, a capability lost after the quake and tsunami.

Nuclear experts say that radiation from the core of a reactor can split water molecules in two, releasing hydrogen. Mr. Wilmshurst said that since the March 26 document, engineers had calculated that the amount of hydrogen produced would be small. But Jay A. LaVerne, a physicist at Notre Dame, said that at least near the fuel rods, some hydrogen would in fact be produced, and could react with oxygen. “If so,” Mr. LaVerne said in an interview, “you have an explosive mixture being formed near the fuel rods.”

Nuclear engineers have warned in recent days that the pools outside the containment buildings that hold spent fuel rods could pose an even greater danger than the melted reactor cores. The pools, which sit atop the reactor buildings and are meant to keep spent fuel submerged in water, have lost their cooling systems.

The N.R.C. report suggests that the fuel pool of the No. 4 reactor suffered a hydrogen explosion early in the Japanese crisis and could have shed much radioactive material into the environment, what it calls “a major source term release.”

Experts worry about the fuel pools because explosions have torn away their roofs and exposed their radioactive contents. By contrast, reactors have strong containment vessels that stand a better chance of bottling up radiation from a meltdown of the fuel in the reactor core.

“Even the best juggler in the world can get too many balls up in the air,” Mr. Lochbaum said of the multiplicity of problems at the plant. “They’ve got a lot of nasty things to negotiate in the future, and one missed step could make the situation much, much worse.”